The experimental results show that the surface structure of the activated carbon material modified by FeSO changes: the specific surface area decreases, the surface oxygen content increases, the plane of the random layer graphite carbon net is destroyed to a certain extent, and the ammonia absorption capacity and benzene absorption performance of the sample are greatly enhanced.He ChunHong et al. [reported the research progress of supporting activated carbon materials in the removal of SO; the removal ability of SO was significantly enhanced after supporting Co, Ni, Mg, and V compounds, which was due to the formation of Co(OH)2, Ni(OH)2, Mg (OH)2, and V,0 microcrystals on the surface of activated carbon after supporting, which enhanced the desulfurization activity of activated carbon.Under certain operating conditions, the gas mixture by adsorption bed, adsorption by adsorption, adsorption after a period of time, when starting from the adsorbent in the laminar flow of the gas adsorbed mass (or its concentration reaches a specified value), think bed fire, adsorption properties of adsorbent adsorption quantity at this time is called dynamic activity of adsorbent.
The activity is not only related to the characteristics of adsorbents and adsorbents, but also related to temperature, concentration and operating conditions.
The kinetic activity value of adsorbent is the main basis for the design of adsorption system.
The adsorption rateThe adsorption process often takes a long time to reach equilibrium, and the contact time is limited in the actual production process.Therefore, the amount of adsorption depends on the adsorption rate, and the adsorption rate is related to the adsorption process, the adsorption process can be divided intoThe adsorption process often takes a long time to reach equilibrium, and the contact time is limited in the actual production process.Therefore, the amount of adsorption depends on the adsorption rate, and the adsorption rate is related to the adsorption process, which can be divided into the following steps
(1) External diffusion, the adsorbate from the main air flow through the air film around the particles to the outer surface of the adsorbent; (2) Internal diffusion, the adsorbate from the outer surface through micropores to the surface of the adsorbent micropores
(3) adsorption, the adsorbent reached the microporous surface of the adsorbent is adsorbed
(4) The desorbed adsorbate diffuses to the main body of the gas phase through internal and external diffusionPhysical adsorption process is generally controlled by internal and external diffusion, chemical adsorption is controlled by both surface dynamics and internal and external diffusion.Because of the complexity of the adsorption process and many influencing factors, it is difficult to derive the rate theoretically, so it is generally determined by experience or model experiment.