The experimental results show that the adsorption equilibrium of pure components is in good agreement with the Langmuir equation.
In the case of multi-component adsorption, due to the competition and interference between each component, the component with strong adsorption ability can replace the other component that has been absorbed, so that the penetration curve of each component has obvious changes.
The penetration point of the components with relatively weak adsorption capacity was significantly advanced, while the penetration time of the components with strong adsorption capacity was delayed.
In this paper, E-L equation and IAST theory are used for theoretical prediction and analysis of multi-component adsorption equilibrium, and compared with experimental results.
The results show that although the prediction of total adsorption amount by E-L equation is in good agreement with the experimental results, the prediction of each component adsorption amount by E-L equation often produces positive and negative deviation, and the average error is usually more than 20%.
However, IAST can eliminate the positive and negative deviation well, and the average error is less than 10%, which is more consistent with the experimental results.
The operating parameters showed that the adsorption capacity of activated carbon would decrease with the increase of temperature, gas velocity or humidity.
The appropriate operating range is: temperature within 40℃, gas speed between 0.1~0.5 m/s, humidity is best not more than 40%.
In this range, the relationship between pressure drop and gas velocity basically conforms to Ergun equation.In order to provide reference and theoretical basis for the preparation and selection of activated carbon for the adsorption of dioxins, this paper carried out a study on the combined technology of activated carbon injection and double bag dust collector, the characteristics of activated carbon adsorption for dioxins and the influencing factors of activated carbon adsorption for dioxins.The adsorption and desorption isotherms of 13 kinds of commercial activated carbon were determined by low temperature nitrogen adsorption method, and the physical structures of activated carbon were calculated according to BET, T-Plot, BJH and DFT theory, and the iodine value and methylene blue value of 4 kinds of activated carbon were detected.
The physical structure characteristics of activated carbon were analyzed in detail to prepare for the subsequent experiment.
Using small activated carbon fixed bed adsorption gas phase dioxin test bench, a typical activated carbon adsorption dioxin factors affecting the experimental study, discusses the types of dioxin adsorption activated carbon and activated carbon fixed bed adsorption gas phase characteristics of dioxins, and discusses the adsorption temperature and adsorption time of activated carbon adsorption of dioxins.The results showed that the specific surface area and micropore volume of activated carbon had weak correlation with the adsorption efficiency of dioxins.
The mesopore volume of activated carbon is an important factor to determine the adsorption capacity of dioxins. The surface area of the pore size between 2 nm and 20nm plays a key role in the adsorption of dioxins.The higher the adsorption temperature, the lower the adsorption efficiency of activated carbon.The longer the adsorption time, the lower the adsorption efficiency of activated carbon.There is no selective adsorption of gaseous dioxins in activated carbon fixed bed.