The kinetic activity value of adsorbent is the main basis for the design of adsorption system.
The adsorption rateThe adsorption process often takes a long time to reach equilibrium, and the contact time is limited in the actual production process.Therefore, the amount of adsorption depends on the adsorption rate, and the adsorption rate is related to the adsorption process, the adsorption process can be divided intoThe adsorption process often takes a long time to reach equilibrium, and the contact time is limited in the actual production process.Therefore, the amount of adsorption depends on the adsorption rate, and the adsorption rate is related to the adsorption process, which can be divided into the following steps:
(1) External diffusion, the adsorbate from the main air flow through the air film around the partic
https://www.dxdcarbon.com/les to the outer surface of the adsorbent; (2) Internal diffusion, the adsorbate from the outer surface through micropores to the surface of the adsorbent micropores
(3) adsorption, the adsorbent reached the microporous surface of the adsorbent is adsorbed
(4) The desorbed adsorbate diffuses to the main body of the gas phase through internal and external diffusionPhysical adsorption process is generally controlled by internal and external diffusion, chemical adsorption is controlled by both surface dynamics and internal and external diffusion.Because of the complexity of the adsorption process and many influencing factors, it is difficult to derive the rate theoretically, so it is generally determined by experience or model experiment.Microwave method, microwave method is not independent of the physical method and chemical method of the preparation of activated carbon, but on the basis of the physical method and chemical method instead of the traditional heating method, but it has a very significant effect.
Microwave refers to the electromagnetic radiation located between far-infrared and radio waves in the electromagnetic spectrum, with a frequency range of 300MHz to 300GHz and a wavelength of 1m to 1mmMicrowave generates "internal friction heat" through high frequency reciprocating motion of dipole molecules in the heated body, which raises the temperature of the material. It does not require any heat conduction process, and has the characteristics of high efficiency, selectivity, non-contact, integrity, uniformity, quick start and stop, and easy operation Studies have shown that activated carbon can effectively absorb microwave energy and make the temperature rise to 110o℃5' within a few minutes.As one of the means of harmless waste treatment, incineration method can quickly realize the reduction of waste, harmless and recycling, so it has been more and more widely used in China.
In the process of waste incineration, toxic organic compounds such as dioxins are inevitably produced, which causes environmental pollution problems.
Activated carbon powder injection combined with bag dust collector (ACI+ BF) is an effective and widely used method to control dioxin emission from incinerator flue gas.
In order to provide reference and theoretical basis for the preparation and selection of activated carbon for the adsorption of dioxins, this paper carried out a study on the combined technology of activated carbon injection and double bag dust collector, the characteristics of activated carbon adsorption for dioxins and the influencing factors of activated carbon adsorption for dioxins.The adsorption and desorption isotherms of 13 kinds of commercial activated carbon were determined by low temperature nitrogen adsorption method, and the physical structures of activated carbon were calculated according to BET, T-Plot, BJH and DFT theory, and the iodine value and methylene blue value of 4 kinds of activated carbon were detected.
The physical structure characteristics of activated carbon were analyzed in detail to prepare for the subsequent experiment.wood based activated carbon manufacturer